Organic electric element, display panel comprising the same and display device comprising the same

ABSTRACT

An organic electric element, a display panel, and a display device including the organic electric element are provided. The organic electric element includes a charge generating layer including a first layer comprising a first compound and a second compound and a second layer comprising a third compound so that they may have excellent efficiency or lifespan.

CROSS REFERENCE TO RELATED APPLICATION

This application claims priority from Korean Patent Application No.10-2019-0180017, filed on Dec. 31, 2019, which is hereby incorporated byreference for all purposes as if fully set forth herein.

BACKGROUND Technical Field

Embodiments of the present disclosure relate to an organic electricelement, a display panel, and a display device including the organicelectric element.

DISCUSSION OF THE RELATED ART

In general, an organic light emitting phenomenon refers to thephenomenon of converting electrical energy into light energy by means ofan organic material. An organic electric element refers to an electricelement using the organic light emitting phenomenon.

An organic electric element using the organic light emitting phenomenonmay be applied to a display device. Since the portable display device isdriven by a battery, which is a limited power source, an organicelectric element used in the portable display device requires excellentlight emission efficiency. In addition, since the image should bedisplayed normally during use of the electronic device, a long life ofthe organic electric element may be also required.

In order to improve efficiency, lifespan and driving voltage in theorganic electric element, research has been conducted on the organicmaterial included in the organic electric element.

SUMMARY

Accordingly, embodiments of the present disclosure are directed to anorganic electric element, a display panel, and a display deviceincluding the organic electric element that substantially obviate one ormore of the problems due to limitations and disadvantages of the relatedart.

An aspect of the present disclosure is to provide an organic electricelement having high efficiency or long life.

Another aspect of the present disclosure is to provide a display panelhaving high efficiency or long life by including the above-describedorganic electric element.

Another aspect of the present disclosure is to provide a display devicehaving high efficiency or long life by including the above-describeddisplay panel.

Additional features and aspects will be set forth in the descriptionthat follows, and in part will be apparent from the description, or maybe learned by practice of the inventive concepts provided herein. Otherfeatures and aspects of the inventive concepts may be realized andattained by the structure particularly pointed out in the writtendescription, or derivable therefrom, and the claims hereof as well asthe appended drawings.

To achieve these and other aspects of the inventive concepts, asembodied and broadly described, an organic electric element comprises afirst electrode, a second electrode and an organic layer.

The organic layer is positioned between the first electrode and thesecond electrode.

The organic layer comprises a first stack comprising a first emittinglayer, a second stack comprising a second emitting layer, and a chargegenerating layer positioned between the first stack and the secondstack.

The charge generating layer comprises a first layer and a second layer.

The first layer comprises a first compound and a second compound.

The first compound is represented by one or more of the followingchemical formula 1 and chemical formula 2.

The second compound is represented by the following chemical formula 3.

The second layer comprises a third compound represented by the followingchemical formula 4.

In another aspect, a display panel comprises a subpixel comprising theorganic electric element.

In another aspect, a display device comprises the display panel and adriving circuit for driving the display panel.

According to embodiments, it is possible to provide the organic electricdevice having high luminous efficiency and long life.

According to embodiments, it is possible to provide a display panelincluding the organic electric device having a high luminous efficiencyand long life and a display device comprising the same.

It is to be understood that both the foregoing general description andthe following detailed description are exemplary and explanatory and areintended to provide further explanation of the inventive concepts asclaimed.

BRIEF DESCRIPTION OF DRAWINGS

The accompanying drawings, which are included to provide a furtherunderstanding of the disclosure and are incorporated in and constitute apart of this application, illustrate embodiments of the disclosure andtogether with the description serve to explain various principles. Inthe drawings:

FIG. 1 is a system configuration diagram of a display device accordingto embodiments;

FIG. 2 is a view illustrating a subpixel circuit of a display panelaccording to embodiments; and

FIG. 3 is a schematic cross-sectional view of an organic electric deviceaccording to embodiments.

DETAILED DESCRIPTION

In the following description of examples or embodiments of the presentinvention, reference will be made to the accompanying drawings in whichit is shown by way of illustration specific examples or embodiments thatcan be implemented, and in which the same reference numerals and signscan be used to designate the same or like components even when they areshown in different accompanying drawings from one another. Further, inthe following description of examples or embodiments of the presentinvention, detailed descriptions of well-known functions and componentsincorporated herein will be omitted when it is determined that thedescription may make the subject matter in some embodiments of thepresent invention rather unclear. The terms such as “including”,“having”, “containing”, “constituting” “make up of”, and “formed of”used herein are generally intended to allow other components to be addedunless the terms are used with the term “only”. As used herein, singularforms are intended to include plural forms unless the context clearlyindicates otherwise.

Terms, such as “first”, “second”, “A”, “B”, “(A)”, or “(B)” may be usedherein to describe elements of the present invention. Each of theseterms is not used to define essence, order, sequence, or number ofelements etc., but is used merely to distinguish the correspondingelement from other elements.

When it is mentioned that a first element “is connected or coupled to”,“contacts or overlaps” etc. a second element, it should be interpretedthat, not only can the first element “be directly connected or coupledto” or “directly contact or overlap” the second element, but a thirdelement can also be “interposed” between the first and second elements,or the first and second elements can “be connected or coupled to”,“contact or overlap”, etc. each other via a fourth element. Here, thesecond element may be included in at least one of two or more elementsthat “are connected or coupled to”, “contact or overlap”, etc. eachother.

When time relative terms, such as “after,” “subsequent to,” “next,”“before,” and the like, are used to describe processes or operations ofelements or configurations, or flows or steps in operating, processing,manufacturing methods, these terms may be used to describenon-consecutive or non-sequential processes or operations unless theterm “directly” or “immediately” is used together.

In addition, when any dimensions, relative sizes etc. are mentioned, itshould be considered that numerical values for an elements or features,or corresponding information (e.g., level, range, etc.) include atolerance or error range that may be caused by various factors (e.g.,process factors, internal or external impact, noise, etc.) even when arelevant description is not specified. Further, the term “may” fullyencompasses all the meanings of the term “can”.

The term “halo” or “halogen” as used herein refers to fluorine (F),bromine (Br), chlorine (Cl), or iodine (I) unless otherwise indicated.

As used herein, the term “alkyl” or “alkyl group” refers to a saturatedaliphatic functional radical of 1 to 60 carbon atoms with a single bondtherein, including a straight chain alkyl group, a branched chain alkylgroup, a cycloalkyl (alicyclic) group, an alkyl-substituted cycloalkylgroup, and a cycloalkyl-substituted alkyl group, unless otherwiseindicated.

The term “haloalkyl group” or “halogenalkyl group”, as used herein,means a halogen-substituted alkyl group unless otherwise specified.

The term “heteroalkyl group”, as used herein, means that at least one ofthe carbon atoms constituting the alkyl group has been replaced with aheteroatom.

As used herein, the terms “alkenyl group” and “alkynyl group”, refer toa straight or branched chain of 2 to 60 carbon atoms with a double and atriple bond therein, respectively, unless stated otherwise, but are notlimited thereto.

Unless otherwise stated, the term “cycloalkyl” as used herein refers toan alkyl forming a ring having 3 to 60 carbon atoms, without beinglimited thereto.

Unless otherwise stated, the term “alkoxyl group”, “alkoxy group”, or“alkyloxy group” as used herein means an alkyl group of 1 to 60 carbonatoms having an oxygen radical attached thereto, but is not limitedthereto.

As used herein, the term “alkenoxyl group”, “alkenoxy group”,“alkenyloxyl group”, or “alkenyloxy group” means an alkenyl group of 2to 60 carbon atoms having an oxygen radical attached thereto, unlessotherwise stated, but is not limited thereto.

As used herein, the term “aryloxyl group” or “aryloxy group” means anaryl group of 6 to 60 carbon atoms having an oxygen radical attachedthereto unless otherwise specified, but is not limited thereto.

As used herein, the terms “aryl group” and “arylene group” each refer tohaving 6 to 60 carbon atoms unless otherwise stated, but are not limitedthereto. In the present disclosure, an aryl group or an arylene groupmeans a single or multiple aromatic ring, including an aromatic ringwhich is formed as neighboring substituents participate in a bond or areaction. For example, the aryl group may be a phenyl group, a biphenylgroup, a terphenyl group, a naphthyl group, an anthracenyl group, afluorene group, a spirofluorene group, or a spirobifluorene group.

The prefix “aryl” or “ar” means a radical substituted with an arylgroup. For example, an arylalkyl group is an alkyl group substitutedwith an aryl group and an arylalkenyl group is an alkenyl groupsubstituted with an aryl group. In this regard, the radical substitutedwith an aryl group has the number of carbon atoms described herein.

Also, when prefixes are named consecutively, it means that thesubstituents are listed in the order described first. By way of example,an arylalkoxy group means an alkoxy group substituted with an arylgroup, an alkoxylcarbonyl group means a carbonyl group substituted withan alkoxyl group, and an arylcarbonylalkenyl group means an alkenylgroup substituted with an arylcarbonyl group wherein the arylcarbonylgroup is a carbonyl group substituted with an aryl group.

As used herein, the term “heteroalkyl” means an alkyl bearing one ormore heteroatoms unless otherwise indicated. As used herein, the terms“heteroaryl group” and “heteroarylene group” refer respectively to anaryl group and an arylene group of 2 to 60 carbon atoms bearing one ormore heteroatoms therein, unless otherwise specified, without beinglimited thereto. It may include at least one of a single ring andmultiple rings, and may be formed by combining adjacent functionalgroups.

Unless otherwise indicated, the term “heterocyclic group” as usedherein, refers to at least one of heteroaliphatic rings andheteroaromatic rings of 2 to 60 carbon atoms bearing one or moreheteroatoms as a ring member thereof, which may be mono- or multi-cyclicand may be formed as neighboring functional groups combine with eachother.

The term “heteroatom” as used herein refers to N, O, S, P, or Si unlessotherwise stated.

“Heterocyclic groups” may also include rings comprising SO2, in place ofcarbon atoms, as a ring member. For example, a “heterocyclic group”includes the following compounds.

Unless otherwise stated, the term “aliphatic” as used herein means analiphatic hydrocarbon of 1 to 60 carbon atoms, and the “aliphatic ring”means an aliphatic hydrocarbon ring of 3 to 60 carbon atoms.

Unless otherwise stated, the term “ring” as used herein refers to analiphatic ring of 3 to 60 carbon atoms, an aromatic ring of 6 to 60carbon atoms, a hetero ring of 2 to 60 carbon atoms, or a fused ringconsisting of a combination thereof whether or not it is saturated orunsaturated.

Other hetero-compounds or hetero-radicals other than the aforementionedhetero-compounds include, but are not limited to, one or moreheteroatoms.

Unless otherwise stated, the term “carbonyl” as used herein isrepresented by —COR′, wherein R′ is hydrogen, an alkyl group of 1 to 20carbon atoms, an aryl group of 6 to 30 carbon atoms, a cycloalkyl groupof 3 to 30 carbon atoms, an alkenyl group of 2 to 20 carbon atoms, analkynyl group of 2 to 20 carbon atoms, or a combination thereof.

Unless otherwise specified, the term “ether” as used herein isrepresented by —R—O—R′, wherein R and R′ are each independentlyhydrogen, an alkyl group of 1 to 20 carbon atoms, an aryl group of 6 to30 carbon atoms, a cycloalkyl group of 3 to 30 carbon atoms, an alkenylgroup of 2 to 20 carbon atoms, an alkynyl group of 2 to 20 carbon atoms,or a combination thereof.

Also, unless explicitly stated otherwise, the term “substituted” in theexpression “substituted or unsubstituted” means having at least onesubstituent selected from the group consisting of, but not limited to,deuterium, halogen, an amino group, a nitrile group, a nitro group, aC1-C20 alkyl group, a C1-C20 alkoxyl group, a C1-C20 alkylamine group, aC1-C20 alkylthiophene group, a C6-C20 arylthiophene group, a C2-C20alkenyl group, a C2-C20 alkynyl, a C3-C20 cycloalkyl group, a C6-C20aryl group, a deuterium-substituted C6-C20 aryl group, a C8-C20 arylalkenyl group, a silane group, a boron group, a germanium group, and aC2-C20 hetero-ring.

Also, unless otherwise stated, the chemical formulas used in the presentinvention are as defined for the exponent parts of the substituent inthe following chemical formula:

wherein,

when a is an integer of 0, the substituent R1 being null,

when a is an integer of 1, one substituent R1 is bonded to any one ofthe constituent carbon atoms of the benzene ring,

when a is an integer of 2 or 3, the substituents R1's, which may be thesame or different, are each bonded as represented below, and

when a is an integer of 4 to 6, the substituents R1's are bonded to theconstituents carbon atoms of the benzene ring in the same manner

while the hydrogens bonded to the constituent carbon atoms of thebenzene ring are not indicated:

In the present specification, the formation of a ring by combiningsubstituents with each other means that adjacent groups combine witheach other to form a monocycle or single ring, a ring aggregated or aconjugated multi-cycle, and the monocycle, the ring aggregated and theformed conjugated multicycle may include the heterocycle including atleast one heteroatom, and may include aromatic and non-aromatic rings.

In the present specification, the organic electric element may mean acomponent (s) between an anode and a cathode, or an organic lightemitting diode including the anode, the cathode and the component(s)positioned therebetween.

In the present specification, the organic electric element may mean oneof an organic electric device, the organic light emitting diode and thepanel including the same, and an electronic device including the paneland a circuit. For example, the electronic device includes a displaydevice, a lighting device, a solar cell, a portable or mobile terminal(eg, a smart phone, a tablet, a PDA, an electronic dictionary, a PMP,etc.), a navigation terminal, a game machine, various TVs, and variouscomputers monitor and the like, but is not limited thereto, and may beany type of device as long as the component (s) are included.

Hereinafter, exemplary embodiments of the present disclosure will bedescribed in detail with reference to the accompanying drawings.

FIG. 1 is a system configuration diagram of a display device accordingto embodiments.

Referring to FIG. 1, the display device 100 in accordance withembodiments of the present disclosure includes a display panel 110 inwhich a plurality of data lines DL and a plurality of gate lines GL arearranged and a plurality of sub-pixels 111 defined by the plurality ofdata lines DL and the plurality of gate lines GL is arranged, a datadriving circuit DDC (or a data driver) for driving the plurality of datalines DL, a gate driving circuit GDC (or a gate driver) for driving theplurality of gate lines GL, a controller D-CTR controlling the datadriving circuit DDC and the gate driving circuit GDC, and the like.

The controller D-CTR controls operations of the data driving circuit DDCand the gate driving circuit GDC by supplying respective control signals(DCS, GCS) to the data driving circuit DDC and the gate driving circuitGDC.

The controller D-CTR starts the scan of pixels according to timingsprocessed in each frame, converts image data inputted from other devicesor other image providing sources to be adapted to a data signal formused in the data driving circuit DDC and then outputs image data DATAresulted from the converting, and causes the data to be loaded into thepixels at a pre-configured time according to the scan.

The controller D-CTR may be implemented as a separate component from thedata driving circuit DDC or may be integrated with data driving circuitDDC so the controller D-CTR can be implemented as an integrated circuit.

The data driving circuit DDC drives the plurality of data lines DL byproviding data voltages corresponding to image data DATA received fromthe controller D-CTR to the data lines DL. Here, the data drivingcircuit DDC is sometimes referred to as a source driving circuit or asource driver.

The data driving circuit DDC may include at least one source driverintegrated circuit SDIC to be implemented.

Each source driver integrated circuit SDIC may include a shift register,a latch circuit, a digital to analog converter DAC, an output buffer,and/or the like.

In some instances, each source driver integrated circuit SDIC mayfurther include one or more analog to digital converters ADC.

The gate driving circuit GDC sequentially drives a plurality of gatelines GL by sequentially providing scan signals to the plurality of gatelines GL. Here, the gate driving circuit GDC is sometimes referred to asa scan driving circuit or a scan driver.

The gate driving circuit GDC may include at least one gate driverintegrated circuit GDIC to be implemented.

Each gate driver integrated circuit GDIC may include a shift register, alevel shifter, and/or the like.

Each gate driver integrated circuit GDIC may be connected to a bondingpad of the display panel 110 in a tape automated bonding (TAB) type or achip on glass (COG) type, or be directly disposed on the display panel110 as being implemented in a gate in panel (GIP) type. In someinstances, the gate driver integrated circuit GDIC may be disposed to beintegrated with the display panel 110. Further, each gate driverintegrated circuit GDIC may be implemented in a chip on film (COF) typein which the gate driver integrated circuit GDIC is mounted on a filmconnected with the display panel 110.

According to the controlling of the controller D-CTR, the gate drivingcircuit GDC sequentially provides scan signals of an on-voltage or anoff-voltage to the plurality of gate lines GL.

When a specific gate line is asserted by a scan signal from the gatedriving circuit GDC, the data driving circuit DDC converts image dataDATA received from the controller D-CTR into analog data voltages andprovides the obtained analog data voltages to the plurality of datalines DL.

The data driving circuit DDC may be located on, but not limited to, onlyone side (e.g., an upper side or a lower side) of the display panel 110,or in some instances, be located on, but not limited to, two sides(e.g., the upper side and the lower side) of the display panel 110according to driving schemes, panel design schemes, or the like.

The gate driving circuit GDC may be located on, but not limited to, onlyone side (e.g., a left side or a right side) of the panel 110, or insome instances, be located on, but not limited to, two sides (e.g., theleft side and the right side) of the display panel 110 according todriving schemes, panel design schemes, or the like.

The display device 100 according to embodiments of the presentdisclosure may be one of various types of display devices, such as, aliquid crystal display device, an organic light emitting display device,a plasma display device, or the like.

In case the display device 100 according to embodiments of the presentdisclosure is an organic light emitting display device, each sub-pixel111 arranged in the display panel 110 may include circuit components,such as an organic light emitting diode (OLED), which is a self-emissiveelement, a driving transistor for driving the organic light emittingdiode OLED, and the like.

Types of circuit elements and the number of the circuit elementsincluded in each subpixel 111 may be different depending on types of thepanel (e.g., an LCD panel, an OLED panel, etc.), provided functions,design schemes/features, or the like.

FIG. 2 is a view illustrating a subpixel circuit of a display panelaccording to embodiments.

Referring to FIG. 2, each subpixel 111 may include an organic lightemitting diode OLED and a driving transistor DRT for driving the organiclight emitting diode OLED as basic circuit components.

Referring to FIG. 2, each sub-pixel 111 may further include a firsttransistor T1 allowing a data voltage VDATA to be applied to a firstnode N1 corresponding to a gate node of the driving transistor DRT, anda storage capacitor C1 for remaining a data voltage VDATA correspondingto an image signal voltage or a voltage corresponding to this during oneframe time.

The organic light emitting diode OLED may include a first electrode 221(an anode electrode or a cathode electrode), a light emitting layer 222,a second electrode 223 (the cathode electrode or the anode electrode),and the like.

In one embodiment, a low-level voltage EVSS may be applied to the secondelectrode 223 of the organic light emitting diode OLED.

The driving transistor DRT causes the organic light emitting diode OLEDto be driven by providing a driving current to the organic lightemitting diode OLED.

The driving transistor DRT includes a first node N1, a second node N2and a third node N3.

The first node N1 of the driving transistor DRT may be a nodecorresponding to the gate node thereof, and may be electricallyconnected to a source node or a drain node of the first transistor T1.

The second node N2 of the driving transistor DRT may be electricallyconnected to the first electrode 221 of the organic light emitting diodeOLED and may be a source node or a drain node.

The third node N3 of the driving transistor DRT may be the drain node orthe source node as a node to which a driving voltage EVDD is applied,and may be electrically connected to a driving voltage line DVL used tosupply a driving voltage EVDD.

The first transistor T1 may be electrically connected between a dataline DL and the first node N1 of the driving transistor DRT and may becontrolled by a scan signal SCAN that is provided through a gate lineand applied to the gate node of the first transistor T1.

The storage capacitor C1 may be electrically connected between the firstnode N1 and the second node N2 of the driving transistor DRT.

The storage capacitor C1 is an external capacitor intentionally designedto be located outside of the driving transistor DRT, not an internalstorage, such as a parasitic capacitor (e.g., a Cgs, a Cgd) thatpresents between the first node N1 and the second node N2 of the drivingtransistor DRT.

FIG. 3 is a cross-sectional view of a display device according to theembodiments.

Referring to FIG. 3, an organic electric element 320 according to theembodiments includes a first electrode 321 and a second electrode 323,an organic layer 322 positioned therebetween.

The first electrode 321 may be an anode and the second electrode 323 maybe a cathode. In the case of an inverted type, the first electrode 321may be a cathode and the second electrode 323 may be an anode.

For example, the first electrode 321 may be a transparent electrode, andthe second electrode 323 may be a reflective electrode. In anotherexample, the first electrode 321 may be a reflective electrode, and thesecond electrode 323 may be a transparent electrode.

The organic layer 322 may include a plurality of layers which is locatedbetween the first electrode 321 and the second electrode 323 andincludes an organic material.

The organic layer includes a first stack 324, a second stack 325, and acharge generating layer 326 positioned between the first stack 324 andthe second stack 325.

The organic electric element 320 may be a tandem organic electricelement including a plurality of stacks each including a light emittinglayer. The plurality of light emitting layers may be made of the samematerial as each other, or may be made of different materials from eachother.

The first stack 324 includes a first emitting layer 324 a. The firstemitting layer 324 a may include, for example, a host material and adopant.

The first stack 324 may further include a first hole transport layer 324b and a first electron transport layer 324 b.

The first hole transport layer 324 b may be positioned between the firstlight emitting layer 324 a and one of the first electrode 321 and thesecond electrode 323 as an anode electrode. The first electron transportlayer 324 c may be positioned between the first light emitting layer 324a and one of the first electrode 321 and the second electrode 323 as acathode electrode. For example, when the first electrode 321 is theanode electrode and the second electrode 323 is the cathode electrode,the first hole transport layer 324 b may be positioned on the firstelectrode 321, the first light emitting layer 324 a may be positioned onthe first hole transport layer 324 b, and the first electron transportlayer 324 c may be positioned on the first light emitting layer 324 a.

The second stack 325 includes a second emitting layer 325 a. The secondemitting layer 325 a may include, for example, a host material and adopant.

The second stack 325 may further include a second hole transport layer325 b and a second electron transport layer 324 b.

The second hole transport layer 325 b may be positioned between thesecond light emitting layer 325 a and one of the first electrode 321 andthe second electrode 323 as an anode electrode. The second electrontransport layer 325 c may be positioned between the second lightemitting layer 324 a and one of the first electrode 321 and the secondelectrode 323 as a cathode electrode. For example, when the firstelectrode 321 is the anode electrode and the second electrode 323 is thecathode electrode, the second hole transport layer 325 b may bepositioned on the second electrode 321, the second light emitting layer325 a may be positioned on the second hole transport layer 325 b, andthe second electron transport layer 324 c may be positioned on thesecond light emitting layer 325 a.

Since the first stack 324 and the second stack 325 are configured asdescribed above, holes and electrons transmitted from the firstelectrode 321 and the second electrode 323 are recombined with eachother in the first and second light emitting layers 324 a and 232 sothat tight may be emitted from by recombination the first and secondlight emitting layers 324 a and 232.

The charge generating layer 326 is formed between a plurality of lightemitting layers to smoothly distribute charges so that it may increasethe current efficiency of the light emitting layer. Accordingly, thecharge generating layer 326 is positioned between the first stack 324including the first light emitting layer 324 a and the second stack 325including the second light emitting layer 325 a.

The charge generating layer 326 may include a p-type charge generatinglayer and an n-type charge generating layer in order to smoothlydistribute charges. For example, the first layer 326 a may be a p-typecharge generating layer and the second layer 326 b may be an n-typecharge generating layer. When the first electrode 321 is the anodeelectrode and the second electrode 323 is the cathode electrode, thep-type charge generating layer may be located on the cathode electrodeside and the n-type charge generating layer may be located on the anodeside. For example, the first layer 326 a may be positioned between thesecond layer 326 b and the second electrode 323 which is a cathodeelectrode.

Although FIG. 3 shows the tandem organic electric element including twostacks, the embodiment is not limited to the tandem organic electricelement including two stacks, and includes tandem organic electricelement including two or more stacks. When the organic electricalelement 320 further includes a stack, a charge generating layer may beadditionally positioned between the additionally included stack and oneof the adjacent first stack 324 and the second stack 325.

The organic electric element 320 may include a hole injection layer 327.The hole injection layer 327 may be positioned between the firstelectrode 321 as an anode electrode and the first light emitting layer324 a. For example, the hole injection layer 327 may be positionedbetween the first electrode 321 as an anode electrode and the first holetransport layer 324 b.

Although not illustrated in FIG. 3, the organic electric element 320 mayfurther include an electron injection layer. For example, the electroninjection layer may be positioned between the second electrode 323 as acathode electrode, and the second electron transport layer 325 c.

In another example, each of the first stack 324 and the second stack 325may further include one or more of a hole injection layer and anelectron injection layer. Within each stack, the hole injection layermay be located between the light emitting layer and the anode electrode,and an electron injection layer may be located between the lightemitting layer and the cathode electrode.

The first layer 326 a includes the first compound. The first holetransport layer 324 b may include the first compound, and the secondhole transport layer 325 b may also include the first compound. Further,the hole injection layer may also include the first compound. The firstcompound included in each layer may be the same as each other or may bedifferent from each other as long as the requirements for the firstcompound described later are met.

The first compound is represented by one or more of the followingchemical formula 1 and chemical formula 2.

Hereinafter, chemical formula 1 and chemical formula 2 will bedescribed.

R₁ to R₆, which are same or different, are each independently oneselected from the group consisting of a hydrogen; a deuterium; atritium; a halogen; a cyano group; a nitro group; a C₆-C₆₀ aryl group; afluorenyl group; a C₂-C₆₀ hetero ring group containing at least onehetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; a C₁-C₅₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₁-C₃₀ alkoxy group; aC₆-C₃₀ aryloxy group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group, and one or more of R₁ to R₆ isthe cyano group.

When R₁ to R₆ are the aryl groups, they may be each independently aC₆-C₆₀ aryl group, a C₆-C₃₀ aryl group or a C₆-C₁₂ aryl group.

A₁ to A₄, which may be the same or different, are each independently oneselected from the group consisting of a hydrogen; a deuterium; atritium; a halogen; a cyano group; a nitro group; a C₆-C₆₀ aryl group; afluorenyl group; a C₂-C₆₀ hetero ring group containing at least onehetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; a C₁-C₆₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₁-C₃₀ alkoxy group; aC₆-C₃₀ aryloxy group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group.

In R₁ to R₆ and A₁ to A₄ of the chemical formula 1 and the chemicalformula 2, the aryl group, the fluorenyl group, the hetero ring group,the fused ring group, the alkyl group, the alkenyl group, the alkynylgroup, the alkoxy group, the aryloxy group, the alkylsilyl group, thearylsilyl group and the alkylarylsilyl group may each be furthersubstituted with at least one substituent selected from the groupconsisting of a deuterium; a nitro group; a cyano group; a halogen; anamino group; a C₁-C₂₀ alkoxyl group; a C₁-C₂₀ alkyl group; a C₂-C₂₀alkenyl group; a C₂-C₂₀ alkynyl group; a C₆-C₂₀ aryl group; a C₆-C₂₀aryl group substituted with the deuterium; a fluorenyl group; a C₂-C₂₀hetero ring group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilyl group;and a C₈-C₆₀ alkylarylsilyl group.

When the first compound is represented by one or more of the chemicalformula 1 and the chemical formula 2, for example, the first layerincludes one compound (A) represented by chemical formula 1 and onecompound (B) represented by chemical formula 2, it means that all thetwo compounds (A, B) are included in the first compound.

The first layer 326 b includes a second compound. The second compound isrepresented by the following chemical formula 3.

Hereinafter, chemical formula 3 will be described.

R₁ and R₂, which may be the same or different, are each independentlyone selected from the group consisting of a C₆-C₆₀ aryl group; afluorenyl group; a C₂-C₆₀ hetero ring group containing at least onehetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; a C₁-C₆₀ alkyl group.

When R₁ and R₂ are the aryl group, they may be each independently theC₆-C₆₀ aryl group, the C₆-C₃₀ aryl group or the C₆-C₁₂ aryl group.

L is one selected from the group consisting of a C₆-C₆₀ arylene group; afluorylene group; a C₂-C₆₀ divalent hetero ring group containing atleast one heteroatom from O, N, S, Si and P; a divalent fused ring groupof a C₃-C₆₀ aliphatic ring and a C₆-C₆₀ aromatic ring.

When L is the aryl group, it may be each independently the C₆-C₆₀ arylgroup, the C₆-C₃₀ aryl group or the C₆-C₁₂ aryl group.

In R₁, R₂, and L of the chemical formula 3, the aryl group, thefluorenyl group, the hetero ring group, the fused ring group, thearylene group, the fluorylene group, the C₂-C₆₀ divalent hetero ringgroup and a divalent fused ring group may each be further substitutedwith at least one substituent selected from the group consisting of adeuterium; a nitro group; a cyano group; a halogen; an amino group; aC₁-C₂₀ alkoxyl group; a C₁-C₂₀ alkyl group; a C₂-C₂₀ alkenyl group; aC₂-C₂₀ alkynyl group; a C₆-C₂₀ aryl group; a C₆-C₂₀ aryl groupsubstituted with the deuterium; a fluorenyl group; a C₂-C₂₀ hetero ringgroup; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilyl group; and aC₈-C₆₀ alkylarylsilyl group.

The second layer 326 b includes a third compound. The third compound maybe represented by the following chemical formula 4.

Hereinafter, chemical formula 4 will be described.

R₁ to R₆, which are same or different, are each independently oneselected from the group consisting of a hydrogen; a deuterium; atritium; a halogen; a cyano group; a nitro group; a C₆-C₆₀ aryl group; afluorenyl group; a C₂-C₆₀ hetero ring group containing at least onehetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; a C₁-C₅₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₁-C₃₀ alkoxy group; aC₆-C₃₀ aryloxy group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group, and one or more of R₁ to R₆ isthe cyano group.

When R₁ to R₆ are the aryl groups, they may be each independently aC₆-C₆₀ aryl group, a C₆-C₃₀ aryl group or a C₆-C₁₂ aryl group.

When R₁ to R₆ are the hetero ring group containing at least one heteroatom from O, N, S, Si and P, they may be each independently the C₆-C₆₀hetero ring group, the C₆-C₅₀ hetero ring group or the C₆-C₄₀ heteroring group.

Ar₁ and Ar₂, which are same or different, are each independently oneselected from the group consisting of a hydrogen; a deuterium; atritium; a halogen; a cyano group; a nitro group; a C₆-C₆₀ aryl group; afluorenyl group; a C₂-C₆₀ hetero ring group containing at least onehetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; a C₁-C₅₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₁-C₃₀ alkoxy group; aC₆-C₃₀ aryloxy group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group, and one or more of R₁ to R₆ isthe cyano group.

When Ar₁ to Ar₆ are the aryl groups, they may be each independently aC₆-C₆₀ aryl group, a C₆-C₅₀ aryl group or a C₆-C₄₀ aryl group.

When Ar₁ to Ar₆ are the hetero ring group containing at least one heteroatom from O, N, S, Si and P, they may be each independently the C₆-C₆₀hetero ring group, the C₆-C₅₀ hetero ring group or the C₆-C₄₀ heteroring group.

L is one selected from the group consisting of a C₆-C₆₀ arylene group; afluorylene group; a C₂-C₆₀ divalent hetero ring group containing atleast one heteroatom from O, N, S, Si and P; a divalent fused ring groupof a C₃-C₆₀ aliphatic ring and a C₆-C₆₀ aromatic ring.

In R₁ to R₆, Ar₁, Ar₂ and L of the chemical formula 4, the aryl group,the fluorenyl group, the hetero ring group, the fused ring group, thealkyl group, the alkenyl group, the alkynyl group, the alkoxy group, thearyloxy group, the alkylsilyl group, the arylsilyl group, thealkylarylsilyl group, the arylene group, the fluorylene group, thedivalent fused ring group, the divalent fused ring group may each befurther substituted with at least one substituent selected from thegroup consisting of a deuterium; a nitro group; a cyano group; ahalogen; an amino group; a C₁-C₂₀ alkoxyl group; a C₁-C₂₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₆-C₂₀ aryl group; aC₆-C₂₀ aryl group substituted with the deuterium; a fluorenyl group; aC₂-C₂₀ hetero ring group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group.

Since the organic electric element 320 includes the first layer 326 aincluding the first compound and the second compound and the secondlayer 326 b including the third compound, it can have high efficiency orlong life.

The first chemical compound is represented by one or more of thefollowing chemical formula 5 and chemical formula 6.

Hereafter, the chemical formula 5 and the chemical formula 6 will bedescribed.

n and m are each independently an integer from 0 to 5.

R₇ to R₈, which may be the same or different, are each independently oneselected from the group consisting of a deuterium; a tritium; a halogen;a cyano group; a C₁-C₅₀ alkyl group; and a C₁-C₃₀ alkoxy group.

When R₇ and R₈ are alkoxy groups, they may be, for example, a C₁-C₃₀alkoxy group, a C₁-C₂₀ alkoxy group or a C₁-C₁₀ alkoxy group.

In R₇ and R₈ of the chemical formula 5 and the chemical formula 6, thealkyl group and the alkoxy group may each be further substituted with atleast one substituent selected from the group consisting of a deuteriumand a halogen.

When the first compound is represented by one or more of the chemicalformula 5 and the chemical formula 6, for example, the first layerincludes one compound (C) represented by chemical formula 5 and onecompound (D) represented by chemical formula 6, it means that all thetwo compounds (C, D) are included in the first compound.

When the first layer 326 a includes the first compound represented byone or more of the above chemical formulas 5 and 6, the organic electricelement 320 may have high efficiency or long life.

The first chemical compound is represented by one or more of thefollowing chemical formula 7 and formula 8.

The chemical formula 7 and the chemical formula 8 will be described.

R₁ to R₆, which are same or different, are each independently oneselected from the group consisting of a hydrogen; a deuterium; atritium; a halogen; a cyano group; a nitro group; a C₆-C₆₀ aryl group; afluorenyl group; a C₂-C₆₀ hetero ring group containing at least onehetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; a C₁-C₅₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₁-C₃₀ alkoxy group; aC₆-C₃₀ aryloxy group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group, and one or more of R₁ to R₆ isthe cyano group.

When R₁ to R₆ are the aryl groups, they may be each independently aC₆-C₆₀ aryl group, a C₆-C₃₀ aryl group or a C₆-C₁₂ aryl group.

In R₁ to R₆ of the chemical formula 7 and the chemical formula 8, thearyl group, the fluorenyl group, the hetero ring group, the fused ringgroup, the alkyl group, the alkenyl group, the alkynyl group, the alkoxygroup, the aryloxy group, the alkylsilyl group, the arylsilyl group andthe alkylarylsilyl group may each be further substituted with at leastone substituent selected from the group consisting of a deuterium; anitro group; a cyano group; a halogen; an amino group; a C₁-C₂₀ alkoxylgroup; a C₁-C₂₀ alkyl group; a C₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynylgroup; a C₆-C₂₀ aryl group; a C₆-C₂₀ aryl group substituted with thedeuterium; a fluorenyl group; a C₂-C₂₀ hetero ring group; a C₃-C₆₀alkylsilyl group; a C₁₈-C₆₀ arylsilyl group; and a C₈-C₆₀ alkylarylsilylgroup.

When the first compound is represented by one or more of the chemicalformula 7 and the chemical formula 8, for example, the first layerincludes one compound (E) represented by chemical formula 7 and onecompound (F) represented by chemical formula 8, it means that all thetwo compounds (E, F) are included in the first compound.

When the first layer 326 a includes the first compound represented byone or more of the above chemical formulas 7 and 8, the organic electricelement 320 may have high efficiency or long life.

The first chemical compound may be one or more of the following chemicalcompounds.

When the first layer 326 a includes the first compound represented byone or more of the above chemical compound, the organic electric element320 may have high efficiency or long life.

The second chemical compound is represented by one or more of thefollowing chemical formula 9.

A-B-A  [chemical formula 9]

Hereafter the chemical formula 9 will be described.

A is the above formula 9-A,

B is one of the following.

In B, * is a position where A is bonded.

In the chemical 9-A, R₁ and R₂, which are same or different, are eachindependently one selected from the group consisting of a C₆-C₆₀ arylgroup; a fluorenyl group; a C₂-C₆₀ hetero ring group containing at leastone hetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; and a C₁-C₅₀ alkyl group.

In R₁ and R₂ of the chemical formula 9-A, the aryl group, the heteroring group, the fused ring group, and the alkyl group, may each befurther substituted with at least one substituent selected from thegroup consisting of a deuterium; a nitro group; a cyano group; ahalogen; an amino group; a C₁-C₂₀ alkoxyl group; a C₁-C₂₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₆-C₂₀ aryl group; aC₆-C₂₀ aryl group substituted with the deuterium; a fluorenyl group; aC₂-C₂₀ hetero ring group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group.

When the first layer 326 a includes the first compound and the secondcompound represented by one or more of the above chemical formula 9, theorganic electric element 320 may have high efficiency or long life.

The second chemical compound may be one or more of the followingchemical compounds.

When the first layer 326 a includes the second compound represented byone or more of the above chemical compound, the organic electric element320 may have high efficiency or long life.

The third chemical compound is one or more of the following chemicalcompounds.

When the first layer 326 a includes the third compound represented byone or more of the above chemical compound, the organic electric element320 may have high efficiency or long life.

The organic electric element 320 satisfies the following general formula1.

L₃-L₁≤2.2 eV  [general formula 1]

In the general formula 1, L₃ is the LUMO (Lowest Unoccupied MolecularOrbital) energy level of the third compound.

L₁ is the LUMO energy level of the first compound.

The upper limit of L₃-L₁ defined in the general formula 1 may be 2.0 eVor less, or 1.8 eV or less.

The organic electric device 320 includes a first layer including a firstcompound satisfying the general formula 1 so that it may have a highefficiency or long life.

The organic electric element 320 satisfies the following general formula2.

L₁-H₂≤2.8 eV  [general formula 2]

In the general formula 2, L₁ is the LUMO (Lowest Unoccupied MolecularOrbital) energy level of the first compound.

H₂ is the HOMO (Highest Occupied Molecular Orbital) energy level of thesecond compound.

The upper limit of L₃-H₂ defined in the general formula 2 may be 2.6 eVor less, or 2.4 eV or less.

The organic electric device 320 includes the first and the second layersincluding the second and the third compounds satisfying the generalformula 2 so that it may have a high efficiency or long life.

The organic electric element 320 satisfies the following general formula3.

0.32 eV≤L₁-H₂≤0.6 eV  [general formula 3]

In the general formula 3, L₁ is the LUMO (Lowest Unoccupied MolecularOrbital) energy level of the first compound.

H₂ is the HOMO (Highest Occupied Molecular Orbital) energy level of thesecond compound.

The lower limit of L₁-H₂ defined in the general formula 3 may be 0.34 eVor more, or 0.38 eV or more.

The upper limit of L₁-H₂ defined in the general formula 3 may be 0.65 eVor less, or 0.50 eV or less.

The organic electric device 320 includes a first layer including thefirst and the second compounds satisfying the general formula 3 so thatit may have a high efficiency or long life.

The first compound included in the first layer 326 a may be a dopant,and the second compound may be a host compound. Since the first layer326 a includes the above-described first compound as the dopant and theabove-described second compound as the host, the first layer 326 a hasexcellent hole transport properties so that the organic electric elementmay have excellent efficiency and lifespan.

The first compound may be doped at the ratio of 10% to 50% by weightinto the first layer 326 a. When the first compound satisfies the aboveratio, the first layer has excellent hole transport properties so thatthe organic electric element may have excellent efficiency and lifespan.

The thickness of the first layer 326 a is not particularly limited, butmay be, for example, 50 Å to 500 Å.

The thickness of the second layer 326 b is not particularly limited, butmay be, for example, 50 Å to 500 Å.

The hole injection layer 327 may include a fourth compound and a fifthcompound.

Details of the fourth compound are the same as those described for thefirst compound described above, unless otherwise specified. Accordingly,the fourth compound may be represented by one or more of the chemicalformulas 1 and 2. In addition, the fourth compound may be represented byone or more of Formula 5 and Formula 6, or may be represented by one ormore of Formula 7 and Formula 8. That is, what has been described forthe first compound can be applied to the fourth compound as it is.

However, the specific fourth compound included in the organic electricelement 320 according to the embodiments may be different from the firstcompound, or may be the same as each other.

Details of the fifth compound are the same as those described for thesecond compound described above, unless otherwise specified. Therefore,the fifth compound may be represented by the chemical formula 3described above. That is, what has been described for the secondcompound may be applied to the fifth compound as it is.

However, the specific fifth compound included in the organic electricelement 320 according to embodiments of the present invention may bedifferent from the second compound, or may be the same as each other.

Since the organic electric element 320 includes a hole injection layer327 including a fourth compound and a fifth compound, it may have highefficiency or long life.

In addition, the fourth compound included in the hole injection layer327 may be a dopant, and the fifth compound may be a host compound. Thehole injection layer 327 includes the above-described fourth compound asthe dopant, and the fifth compound as the host, so that the holeinjection layer 327 has excellent hole injection characteristics so thatthe organic electric element may have excellent efficiency and lifespan.

The fourth compound may be doped at a ratio of 10% to 50% by weight intothe hole injection layer 327. When the fourth compound is doped tosatisfy the above ratio, the hole injection layer 327 has excellent holeinjection characteristics, so that the organic electric element may haveexcellent efficiency and lifespan.

The thickness of the hole injection layer 327 is not particularlylimited, but may be, for example, 50 Å to 500 Å.

Other embodiments of the present invention may provide a display panel110.

The display panel 110 includes a sub-pixel 111 including theabove-described organic electric element 220.

In the display panel 110 according to the present embodiment, since theorganic electrical element 220 is the same as the organic electricalelement 220 according to the above-described embodiments, a descriptionthereof will be omitted.

In addition, since the display panel 110 and the sub-pixel 111 accordingto the embodiments have been described above, a description thereof willbe omitted.

Other embodiments of the present invention 100 may provide a displaydevice.

The display device 100 includes the above-described display panel 110and a driving circuit for driving the above-described display panel 110.

In the display device 100 according to the present embodiments, thedisplay panel 110 is the same as the display panel 110 according to theabove-described embodiments, so a description thereof will be omitted.

In addition, since the driving circuit for driving the display panelaccording to embodiments has been described above, a description thereofwill be omitted.

Hereinafter, examples of manufacturing an organic electric elementaccording to the embodiments will be specifically described withreference to the embodiment, but the embodiments are not limited to thefollowing examples.

Manufacturing Evaluation of Organic Electric Element

Comparative Example 1

After washing a glass substrate coated with ITO (indium tin oxide) to athickness of 1,000 Å, the substrate is washed with a solvent such asisopropyl alcohol, acetone or methanol and dried. On this prepared ITOtransparent electrode, NPD(N,N′-Di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine) is used asthe fifth compound, F4-TCNQ(2,3,5,6-tetrafluoro-tetracyanoquinodimethane) was doped with 10% as thefourth compound and thermally vacuum-deposited to form a hole injectionlayer of 10 nm. A first hole transport layer (HTL1) was formed bythermal vacuum deposition of a hole transport material (NPD) of 100 nm.

Subsequently, a second hole transport layer (HTL2) was formed by thermalvacuum deposition of a hole transport material (TCTA,Tris(4-carbazoyl-9-ylphenyl) amine) to a thickness of 100 nm. Afterthat, ADN(9,10-di(naphtha-2-yl)anthracene) and 1,6-Bis(diphenylamine)pyrene were used as host and dopant materials,respectively, doped with 3%, and thermally vacuum-deposited to athickness of 20 nm to form a first light emitting layer.

Subsequently, a first electron transport layer was formed by thermalvacuum deposition of an electron transport material (TmPyPB, 1,3,5-Tri(m-pyridin-3-ylphenyl) benzene) to a thickness of 10 nm, andBphen(Bathophenanthroline) as the third compound was used, and Li wasdoped with 2% to form a second layer (n-type charge generation layer) bythermal vacuum deposition to a thickness of 20 nm.

Subsequently, NPD (N, N′-Di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine) is used as the second compoundand F4-TCNQ(2,3,5,6-tetrafluoro-tetracyanoquinodimethane) was doped with10% as the first compound and thermally vacuum-deposited to form a firstlayer (p-type charge generation layer) of 10 nm.

Subsequently,NPD(N,N′-Di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine) as ahole transport material was vacuum-deposited to a thickness of 20 nm andthen CBP (4,4′-Bis (N-carbazolyl)-1,1′-biphenyl) is used as a host andIr(ppy)3 (tris(2-phenylpyridine)Iridium (III) was doped with 10% as adopant. Thermal vacuum deposition was performed to form a second lightemitting layer of 20 nm.

Subsequently, a second electron transport layer was formed by thermalvacuum deposition using Alq3 as an electron transport material, and thenthermal vacuum deposition was performed using LiF as an electroninjection material to form an electron injection layer. Subsequently, acathode was formed by depositing A1 to a thickness of 200 nm, therebyfabricating an organic electric element.

Embodiments 1 to 30 and Comparative Examples 2 to 6

The organic electric element was manufactured in the same manner as inthe Comparative Example 1, except that the first compound, the secondcompound, the fourth compound, and the fifth compound were used in thetypes and ratios shown in Tables 1 and 2 below. Tables 3 and 4 show theperformances of the manufactured organic electric elements.

TABLE 1 first second third forth fifth chemical chemical chemicalchemical chemical L₃—L₁ L₃—H₂ L₁—H₂ compound compound compound compoundcompound (eV) (eV) (eV) Comparative F4-TCNQ NPD Bphen F4-TCNQ NPD 2.202.50 0.30 Example 1 (10%) (10%) Comparative F4-TCNQ 25 Bphen F4-TCNQ 252.20 2.23 0.03 Example 2 (10%) (10%) Comparative F4-TCNQ 34 BphenF4-TCNQ 34 2.20 2.19 −0.01 Example 3 (10%) (10%) Comparative F4-TCNQ 60Bphen F4-TCNQ 60 2.20 2.20 0 Example 4 (10%) (10%) Embodiment1 A04 (10%)NPD Bphen A04 (10%) NPD 1.75 2.50 0.75 Embodiment2 A04 (10%) 25 BphenA04 (10%) 25 1.75 2.23 0.48 Embodiment3 A04 (10%) 34 Bphen A04 (10%) 341.75 2.19 0.44 Embodiment4 A04 (10%) 60 Bphen A04 (10%) 60 1.75 2.200.45 Embodiment5 A15 (10%) NPD Bphen A15 (10%) NPD 1.74 2.50 0.76Embodiment6 A15 (10%) 25 Bphen A15 (10%) 25 1.74 2.23 0.49 Embodiment7A15 (10%) 34 Bphen A15 (10%) 34 1.74 2.19 0.45 Embodiment8 A15 (10%) 60Bphen A15 (10%) 60 1.80 2.20 0.46 Embodiment9 A38 (10%) NPD Bphen A38(10%) NPD 1.80 2.50 0.30 Embodiment10 A38 (10%) 25 Bphen A38 (10%) 251.80 2.23 0.57 Embodiment10 A38 (10%) 34 Bphen A38 (10%) 34 1.80 2.190.61 Embodiment10 A38 (10%) 60 Bphen A38 (10%) 60 1.80 2.20 0.60

TABLE 2 second third forth fifth first chemical chemical chemicalchemical chemical L₃—L₁ L₃—H₂ L₁—H₂ compound compound compound compoundcompound (eV) (eV) (eV) Comparative F4-TCNQ NPD Bphen F4-TCNQ NPD 2.202.50 0.30 Example 1 (10%) (10%) Comparative F4-TCNQ NPD Bphen F4-TCNQNPD 2.20 2.50 0.30 Example 5 (20%) (20%) Comparative F4-TCNQ NPD BphenF4-TCNQ NPD 2.20 2.50 0.30 Example 6 (30%) (30%) Embodiment 13 A15 (10%)NPD Bphen A15 (10%) NPD 1.74 2.50 0.76 Embodiment 14 A15 (20%) NPD BphenA15 (20%) NPD 1.74 2.50 0.76 Embodiment 15 A15 (30%) NPD Bphen A15 (30%)NPD 1.74 2.50 0.76 Embodiment 6 A15 (10%) NPD E05 A15 (10%) NPD 1.682.44 0.76 Embodiment 16 A15 (10%) 25 Bphen A15 (10%) 25 1.74 2.23 0.49Embodiment 17 A15 (10%) 25 E05 A15 (10%) 25 1.68 2.17 0.49 Embodiment 18A15 (20%) 25 E05 A15 (20%) 25 1.68 2.17 0.49 Embodiment 19 A15 (30%) 25E05 A15 (30%) 25 1.68 2.17 0.49 Embodiment 20 A15 (10%) 34 E27 A15 (10%)34 1.62 2.07 0.45 Embodiment 21 A15 (20%) 34 E27 A15 (20%) 34 1.62 2.070.45 Embodiment 9 A15 (30%) 34 E27 A15 (30%) 34 1.62 2.07 0.45Embodiment 22 A38 (10%) NPD Bphen A38 (10%) NPD 1.80 2.50 0.70Embodiment 23 A38 (20%) NPD Bphen A38 (20%) NPD 1.80 2.50 0.70Embodiment 24 A38 (30%) NPD Bphen A38 (30%) NPD 1.80 2.50 0.70Embodiment 10 A38 (10%) NPD E05 A38 (10%) NPD 1.74 2.44 0.70 Embodiment25 A38 (10%) 25 Bphen A38 (10%) 25 1.80 2.23 0.57 Embodiment 26 A38(10%) 25 E05 A38 (10%) 25 1.74 2.17 0.57 Embodiment 27 A38 (20%) 25 E05A38 (20%) 25 1.74 2.17 0.57 Embodiment 28 A38 (30%) 25 E05 A38 (30%) 251.74 2.17 0.57 Embodiment 29 A38 (10%) 34 E27 A38 (10%) 34 1.68 2.070.61 Embodiment 30 A38 (20%) 34 E27 A38 (20%) 34 1.68 2.07 0.61

In Tables 1 and 2, A04, A15 and A38 are A04, A15 and A38 chemicalcompounds described as being selectable as the first chemical compound,and 25, 34 and 60 are the second 25, 34 and 60 chemical compoundsdescribed as being selectable as chemical compounds, and E05 and E27 areE05 and E27 chemical compounds described as being selectable as thethird chemical compounds. F4-TCNQ is as follows.

TABLE 3 driving voltage efficiency color coordinate lifespan (V) (cd/A)(CIE x, y) (T95, hr) Comparative 10.7 53.7 0.315 0.332 317 Example 1Comparative 10.4 53.3 0.32 0.331 280 Example 2 Comparative 9.7 54.20.319 0.336 330 Example 3 Comparative 9.9 54.9 0.32 0.333 328 Example 4Embodiment1 9.4 56.4 0.323 0.335 338 Embodiment2 9 57 0.323 0.334 361Embodiment3 8.6 56.9 0.322 0.332 380 Embodiment4 8.8 57.2 0.32 0.331 380Embodiment5 9.3 56.5 0.321 0.334 326 Embodiment6 9 56.9 0.321 0.331 364Embodiment7 8.4 57.6 0.322 0.332 368 Embodiment8 8.8 58.1 0.318 0.33 372Embodiment9 9.2 55.8 0.318 0.338 347 Embodiment10 8.8 56.1 0.318 0.33348 Embodiment11 8.4 57.9 0.321 0.334 374 Embodiment12 8.3 58.2 0.3260.333 391

Table 4 driving voltage efficiency color coordinate lifespan (V) (cd/A)(CIE x, y) (T95, hr) Comparative 10.7 53.7 0.315 0.332 317 Example 1Comparative 10.5 54.1 0.32 0.328 335 Example 5 Comparative 10.2 54 0.3190.331 310 Example 6 Embodiment 13 9.3 56.5 0.321 0.334 326 Embodiment 149.5 55.3 0.319 0.329 334 Embodiment 15 9.4 55.8 0.319 0.326 340Embodiment 6 9 60.3 0.323 0.337 453 Embodiment 16 9 56.9 0.321 0.331 364Embodiment 17 8.4 57.6 0.322 0.332 368 Embodiment 18 8.1 57.8 0.3240.338 397 Embodiment 19 7.9 58.6 0.323 0.34 424 Embodiment 20 9.1 57.40.32 0.335 383 Embodiment 21 8.6 58.2 0.321 0.331 451 Embodiment 9 8.258.5 0.322 0.329 468 Embodiment 22 9.2 55.8 0.318 0.338 347 Embodiment23 9.1 56.4 0.32 0.334 351 Embodiment 24 9.1 56 0.321 0.335 356Embodiment 10 8.9 56.2 0.32 0.334 353 Embodiment 25 8.8 56.1 0.318 0.33348 Embodiment 26 8.4 57.9 0.321 0.334 374 Embodiment 27 8 58.6 0.3180.336 395 Embodiment 28 7.6 58.5 0.326 0.337 412 Embodiment 29 8.8 57.10.323 0.335 384 Embodiment 30 8.3 57.3 0.319 0.336 447

As can be seen from the results of Tables 3 and 4, the organic electricelement according to the embodiments includes the charge generatinglayer including the first layer including the first compound and thesecond compound according to the embodiments and the second layerincluding the third compound so that it may have excellent efficiency orlifespan compared to the organic electric element of the ComparativeExample.

In the case of Embodiments 1, 5 and 9 including the first layerincluding the first compound represented by at least one of the chemicalformula 1 and the chemical formula 2, its efficiency of lifespan isimproved compared to the organic electric element of the ComparativeEmbodiment.

In addition, compared to the Embodiments 1, 5 and 9, it can be seen thatthe organic electric element of the Embodiments including the firstlayer further comprising the second compound represented by the chemicalformula 3 has better efficiency and longer life than the organicelectric elements of Embodiments 1, and 9. In addition, it can be seenthat the organic electric element of the Embodiments comprising thesecond layer containing the third compound represented by the chemicalformula 4 has better efficiency and longer life than the organicelectric elements of Embodiments 1, 5 and 9. In addition, it can be seenthat the organic electric element of the embodiments comprising thefirst layer further comprising a second compound represented by thechemical formula 3 and a second layer comprising a third compoundrepresented by the chemical formula 4 has better efficiency and longerlife than the organic electric elements of Embodiments 1, 5 and 9.

Accordingly, it can be seen that a feature comprising the first compoundrepresented by one or more of the chemical formulas 1 and 2 and thesecond compound represented by the chemical formula 3, and a featurecomprising a third compound represented by the chemical formula 4provide synergistic effects with each other to provide a more excellentorganic electric element.

Further, in the Comparative Examples 1, 5, and 6, the driving voltage,efficiency, and lifespan did not increase even when the doping ratio ofthe p-type doping material was increased, but in the case of theEmbodiment, when the doping ratio of the first chemical compound that isthe p-type doping material was increased, it can be seen that theorganic electric element is improved in terms of the driving voltage,efficiency, or lifespan.

It will be apparent to those skilled in the art that variousmodifications and variations can be made in the present disclosurewithout departing from the technical idea or scope of the disclosure.Thus, it is intended that the present disclosure cover the modificationsand variations of this disclosure provided they come within the scope ofthe appended claims and their equivalents.

What is claimed is:
 1. An organic electric element, comprising: a firstelectrode; a second electrode; and an organic layer positioned betweenthe first electrode and the second electrode, wherein the organic layercomprises a first stack comprising a first emitting layer, a secondstack comprising a second emitting layer, and a charge generating layerpositioned between the first stack and the second stack, the chargegenerating layer comprises a first layer and a second layer, the firstlayer comprises a first compound represented by one or more of thefollowing chemical formula 1 and chemical formula 2 and a secondcompound represented by the following chemical formula 3, and the secondlayer comprises a third compound represented by the following chemicalformula 4:

in the chemical formula 1 and the chemical formula 2, R₁ to R₆, whichare same or different, are each independently one selected from thegroup consisting of a hydrogen; a deuterium; a tritium; a halogen; acyano group; a nitro group; a C₆-C₆₀ aryl group; a fluorenyl group; aC₂-C₆₀ hetero ring group containing at least one hetero atom from O, N,S, Si and P; a fused ring group of a C₃-C₆₀ aliphatic ring and a C₆-C₆₀aromatic ring; a C₁-C₅₀ alkyl group; a C₂-C₂₀ alkenyl group; a C₂-C₂₀alkynyl group; a C₁-C₃₀ alkoxy group; a C₆-C₃₀ aryloxy group; a C₃-C₆₀alkylsilyl group; a C₁₈-C₆₀ arylsilyl group; and a C₈-C₆₀ alkylarylsilylgroup, and one or more of R₁ to R₆ is the cyano group, A₁ to A₄, whichmay be the same or different, are each independently one selected fromthe group consisting of a hydrogen; a deuterium; a tritium; a halogen; acyano group; a nitro group; a C₆-C₆₀ aryl group; a fluorenyl group; aC₂-C₆₀ hetero ring group containing at least one hetero atom from O, N,S, Si and P; a fused ring group of a C₃-C₆₀ aliphatic ring and a C₆-C₆₀aromatic ring; a C₁-C₅₀ alkyl group; a C₂-C₂₀ alkenyl group; a C₂-C₂₀alkynyl group; a C₁-C₃₀ alkoxy group; a C₆-C₃₀ aryloxy group; a C₃-C₆₀alkylsilyl group; a C₁₈-C₆₀ arylsilyl group; and a C₈-C₆₀ alkylarylsilylgroup, In R₁ to R₆ and A₁ to A₄ of the chemical formula 1 and thechemical formula 2, the aryl group, the fluorenyl group, the hetero ringgroup, the fused ring group, the alkyl group, the alkenyl group, thealkynyl group, the alkoxy group, the aryloxy group, the alkylsilylgroup, the arylsilyl group and the alkylarylsilyl group may each befurther substituted with at least one substituent selected from thegroup consisting of a deuterium; a nitro group; a cyano group; ahalogen; an amino group; a C₁-C₂₀ alkoxyl group; a C₁-C₂₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₆-C₂₀ aryl group; aC₆-C₂₀ aryl group substituted with the deuterium; a fluorenyl group; aC₂-C₂₀ hetero ring group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group, in the chemical formula 3, R₁and R₂, which may be the same or different, are each independently oneselected from the group consisting of a C₆-C₆₀ aryl group; a fluorenylgroup; a C₂-C₆₀ hetero ring group containing at least one hetero atomfrom O, N, S, Si and P; a fused ring group of a C₃-C₆₀ aliphatic ringand a C₆-C₆₀ aromatic ring; a C₁-C₆₀ alkyl group, L is one selected fromthe group consisting of a C₆-C₆₀ arylene group; a fluorylene group; aC₂-C₆₀ divalent hetero ring group containing at least one heteroatomfrom O, N, S, Si and P; a divalent fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring, in R₁, R₂, and L of thechemical formula 3, the aryl group, the fluorenyl group, the hetero ringgroup, the fused ring group, the arylene group, the fluorylene group,the C₂-C₆₀ divalent hetero ring group and a divalent fused ring groupmay each be further substituted with at least one substituent selectedfrom the group consisting of a deuterium; a nitro group; a cyano group;a halogen; an amino group; a C₁-C₂₀ alkoxyl group; a C₁-C₂₀ alkyl group;a C₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₆-C₂₀ aryl group; aC₆-C₂₀ aryl group substituted with the deuterium; a fluorenyl group; aC₂-C₂₀ hetero ring group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group, In the chemical formula 4, R₁to R₆, which are same or different, are each independently one selectedfrom the group consisting of a hydrogen; a deuterium; a tritium; ahalogen; a cyano group; a nitro group; a C₆-C₆₀ aryl group; a fluorenylgroup; a C₂-C₆₀ hetero ring group containing at least one hetero atomfrom O, N, S, Si and P; a fused ring group of a C₃-C₆₀ aliphatic ringand a C₆-C₆₀ aromatic ring; a C₁-C₅₀ alkyl group; a C₂-C₂₀ alkenylgroup; a C₂-C₂₀ alkynyl group; a C₁-C₃₀ alkoxy group; a C₆-C₃₀ aryloxygroup; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilyl group; and aC₈-C₆₀ alkylarylsilyl group, and one or more of R₁ to R₆ is the cyanogroup, Ar₁ and Ar₂, which are same or different, are each independentlyone selected from the group consisting of a hydrogen; a deuterium; atritium; a halogen; a cyano group; a nitro group; a C₆-C₆₀ aryl group; afluorenyl group; a C₂-C₆₀ hetero ring group containing at least onehetero atom from O, N, S, Si and P; a fused ring group of a C₃-C₆₀aliphatic ring and a C₆-C₆₀ aromatic ring; a C₁-C₅₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₁-C₃₀ alkoxy group; aC₆-C₃₀ aryloxy group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group, and one or more of R₁ to R₆ isthe cyano group, L is one selected from the group consisting of a C₆-C₆₀arylene group; a fluorylene group; a C₂-C₆₀ divalent hetero ring groupcontaining at least one heteroatom from O, N, S, Si and P; a divalentfused ring group of a C₃-C₆₀ aliphatic ring and a C₆-C₆₀ aromatic ring,and in R₁ to R₆, Ar₁, Ar₂ and L of the chemical formula 4, the arylgroup, the fluorenyl group, the hetero ring group, the fused ring group,the alkyl group, the alkenyl group, the alkynyl group, the alkoxy group,the aryloxy group, the alkylsilyl group, the arylsilyl group, thealkylarylsilyl group, the arylene group, the fluorylene group, thedivalent fused ring group, the divalent fused ring group may each befurther substituted with at least one substituent selected from thegroup consisting of a deuterium; a nitro group; a cyano group; ahalogen; an amino group; a C₁-C₂₀ alkoxyl group; a C₁-C₂₀ alkyl group; aC₂-C₂₀ alkenyl group; a C₂-C₂₀ alkynyl group; a C₆-C₂₀ aryl group; aC₆-C₂₀ aryl group substituted with the deuterium; a fluorenyl group; aC₂-C₂₀ hetero ring group; a C₃-C₆₀ alkylsilyl group; a C₁₈-C₆₀ arylsilylgroup; and a C₈-C₆₀ alkylarylsilyl group.
 2. The organic electricelement according to claim 1, wherein the first chemical compound isrepresented by one or more of the following chemical formula 5 andchemical formula 6:

in the chemical formula 5 and the chemical formula 6, n and m are eachindependently an integer from 0 to 5, R₇ to R₈, which may be the same ordifferent, are each independently one selected from the group consistingof a deuterium; a tritium; a halogen; a cyano group; a C₁-C₅₀ alkylgroup; and a C₁-C₃₀ alkoxy group, and in R₇ and RB of the chemicalformula 5 and the chemical formula 6, the alkyl group and the alkoxygroup may each be further substituted with at least one substituentselected from the group consisting of a deuterium and a halogen.
 3. Theorganic electric element according to claim 1, wherein the firstchemical compound is represented by one or more of the followingchemical formula 7 and formula 8:

in the chemical formula 7 and the chemical formula 8, R₁ to R₆ are thesame as R₁ to R₆ defined in the chemical formulas 1 and
 2. 4. Theorganic electric element according to claim 1, wherein the secondchemical compound is represented by one or more of the followingchemical formula 9:A-B-A  [chemical formula 9] In the chemical 9, A is the above formula9-A,

B is one of the following,

In B, * is a position where A is bonded, In the chemical 9-A, R₁ and R₂are the same as R₁ and R₂ defined in the chemical formula
 3. 5. Theorganic electric element according to claim 1, wherein the firstchemical compound is one or more of the following chemical compounds:


6. The organic electric element according to claim 1, wherein the secondchemical compound is one or more of the following chemical compounds:


7. The organic electric element according to claim 1, wherein the thirdchemical compound is one or more of the following chemical compounds:


8. The organic electric element according to claim 1, wherein the firstelectrode is an anode electrode, the second electrode is a cathodeelectrode, and the first layer is positioned between the second layerand the second electrode.
 9. The organic electric element according toclaim 1, further comprising a hole injection layer located between thefirst electrode and the first light emitting layer, and the electroncomprises a fourth compound represented by one or more of the chemicalformula 1 and the chemical formula 2 and a fifth compound represented bythe chemical formula
 3. 10. The organic electric element according toclaim 1, wherein the fourth compound is the same compound as the firstcompound, and the fifth compound is the same organic compound as thesecond compound.
 11. The organic electric element according to claim 1,wherein the following general formula 1 is satisfied:L₃-L₁≤2.2 eV  [general formula 1] In the general formula 1, L₃ is theLUMO (Lowest Unoccupied Molecular Orbital) energy level of the thirdcompound, and L₁ is the LUMO energy level of the first compound.
 12. Theorganic electric element according to claim 1, wherein the followinggeneral formula 2 is satisfied:L₃-H₂≤2.8 eV  [general formula 2] In the general formula 2, L₃ is theLUMO (Lowest Unoccupied Molecular Orbital) energy level of the thirdcompound, and H₁ is the HOMO(Highest Occupied Molecular Orbital) energylevel of the second compound.
 13. The organic electric element accordingto claim 1, wherein the following general formula 3 is satisfied:0.32 eV≤L₁-H₂≤0.8 eV  [general formula 3] in the general formula 3, L₁is the LUMO (Lowest Unoccupied Molecular Orbital) energy level of thefirst compound, and H₂ is the HOMO(Highest Occupied Molecular Orbital)energy level of the second compound.
 14. A display panel comprising asubpixel comprising the organic electric element of claim
 1. 15. Adisplay device comprising; the display panel of claim 14; and a drivingcircuit for driving the display panel.